HRID1602578

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCOC(=O)c1ccc(C[C@H](c2ccc([N+](=O)[O-])cc2)[C@H](C)O)o1

HCID15458176

未命名化合物

结构：CC(NC/C=C/c1ccccc1)C(Cc1ccc(C(=O)Nc2ccccc2)o1)c1ccc([N+](=O)[O-])cc1

HCID19611724

未命名化合物

PRODUCTS

生成物

结构：C[C@@H](NC/C=C/c1ccccc1)[C@H](Cc1ccc(C(=O)Nc2ccccc2)o1)c1ccc([N+](=O)[O-])cc1

HCID70108212

未命名化合物

PROCEDURE

实验过程

The title compound was prepared in the same manners as in Reference Example 4(3) to (5) by using ethyl 5-{(2R,3S)-3-hydroxy-2-(4-nitrophenyl)butyl}-2-furancarboxylate as the starting material.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e7bfd86b6ff54dd38a4a7e1f09fb0f3a
来源数据集: uspto-grants-1999_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05981573
来源说明: uspto-grants-1999_11

反应 SMILES

[C:1]1(/[CH:7]=[CH:8]/[CH2:9][NH:10][CH:11]([CH3:37])[CH:12]([C:28]2[CH:33]=[CH:32][C:31]([N+:34]([O-:36])=[O:35])=[CH:30][CH:29]=2)[CH2:13][C:14]2[O:15][C:16]([C:19](=[O:27])[NH:20][C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)=[CH:17][CH:18]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.O[C@@H](C)[C@@H](C1C=CC([N+]([O-])=O)=CC=1)CC1OC(C(OCC)=O)=CC=1>>[C:1]1(/[CH:7]=[CH:8]/[CH2:9][NH:10][C@H:11]([CH3:37])[C@@H:12]([C:28]2[CH:33]=[CH:32][C:31]([N+:34]([O-:36])=[O:35])=[CH:30][CH:29]=2)[CH2:13][C:14]2[O:15][C:16]([C:19](=[O:27])[NH:20][C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)=[CH:17][CH:18]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1