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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1602612Generated: November 2, 2026

epsilon-CAPROLACTONE → Cyclohexanol cyclohexanone

https://huagongshe.com/reaction/1602612

Reaction equation

Participants

RoleNameHCIDCharge
Reactantepsilon-CAPROLACTONEHCID 10401—
Reactant1,6-HexanediolHCID 12374—
Reactant6-Hydroxyhexanoic AcidHCID 14490—
SolventCyclohexaneHCID 8078—
ProductCyclohexanol cyclohexanoneHCID 22492587—

Reaction Steps

A process for preparing 1,6-hexanediol and ε-caprolactone from a carboxylic acid mixture comprising adipic acid, 6-hydroxycaproic acid and small amounts of 1,4-cyclohexanediols which is obtained as a by-product in the oxidation of cyclohexane to cyclohexanone/cyclohexanol using oxygen or oxygen-containing gases by water extraction of the reaction mixture, by esterifying and hydrogenating a substream to give hexanediol and cyclizing 6-hydroxycaproic esters to give caprolactone, wherein

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS05981769
Source datasetuspto-grants-1999_11
ORD IDord-ea2d25b7c666470b83456aa930169b13
Source noteuspto-grants-1999_11