HuagongsheHuagongshe Chemistry Print Report · For research reference only
epsilon-CAPROLACTONE → Cyclohexanol cyclohexanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | epsilon-CAPROLACTONE | HCID 10401 | — |
| Reactant | 1,6-Hexanediol | HCID 12374 | — |
| Reactant | 6-Hydroxyhexanoic Acid | HCID 14490 | — |
| Solvent | Cyclohexane | HCID 8078 | — |
| Product | Cyclohexanol cyclohexanone | HCID 22492587 | — |
Reaction Steps
A process for preparing 1,6-hexanediol and ε-caprolactone from a carboxylic acid mixture comprising adipic acid, 6-hydroxycaproic acid and small amounts of 1,4-cyclohexanediols which is obtained as a by-product in the oxidation of cyclohexane to cyclohexanone/cyclohexanol using oxygen or oxygen-containing gases by water extraction of the reaction mixture, by esterifying and hydrogenating a substream to give hexanediol and cyclizing 6-hydroxycaproic esters to give caprolactone, wherein
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05981769 |
| Source dataset | uspto-grants-1999_11 |
| ORD ID | ord-ea2d25b7c666470b83456aa930169b13 |
| Source note | uspto-grants-1999_11 |