HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → EtOAc EtOH H2O NH4OH
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | HCID 86754784 | HCID 86754784 | — |
| Product | EtOAc EtOH H2O NH4OH | HCID 86752451 | — |
| Product | HCID 86754784 | HCID 86754784 | — |
Reaction Steps
A mixture of 7-2 (60 mg, 0.11 mmol), 1N NaOH (132 μL), and ethanol (1 mL) was stirred at ambient temperature for 1 hr, followed by concentration. Flash chromatography (silica, 25:10:1:1 to 15:10:1:1 EtOAc/EtOH/NH4OH/H2O) gave 7-3 as a white solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05981546 |
| Source dataset | uspto-grants-1999_11 |
| ORD ID | ord-6951a14ada524877baa328cdc848907f |
| Source note | uspto-grants-1999_11 |