HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium borohydride → HCID 18394777, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium borohydride | HCID 4311764 | — |
| Reactant | HCID 18394781 | HCID 18394781 | — |
| Solvent | Hexamethylphosphoramide | HCID 12679 | — |
| Product | HCID 18394777 | HCID 18394777 | — |
Reaction Steps
To a stirred solution of 11-5 (900 mg, 6.26 mmol) and HMPA (30 mL) was added NaBH4 (156 mg, 4.20 mmol). After 45 minutes, the reaction was poured into 50 mL 1:1 Et2O/hexanes and then washed with H2O, brine, dried (MgSO4) and concentrated to provide 11-6 as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05981546 |
| Source dataset | uspto-grants-1999_11 |
| ORD ID | ord-8c040bce070e46f09636beec1cb7c049 |
| Source note | uspto-grants-1999_11 |