2-Bromocyclohept-1-ene-1-carbaldehyde → HCID 9841547, compound

HRID 1603268Notes

Reaction equation

HRID 1603268 reaction equation
BrC1CCCCCC=1C=O.C([O:13][C:14](=[O:38])/[CH:15]=[C:16](\[CH3:37])/[CH:17]=[CH:18][C:19]1[CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][C:20]=1[CH:26]=[CH:27][C:28]1[C:33]([CH3:35])([CH3:34])[CH2:32][CH2:31][CH2:30][C:29]=1[CH3:36])C>>[CH3:37]/[C:16](/[CH:17]=[CH:18][C:19]1[CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][C:20]=1[CH:26]=[CH:27][C:28]1[C:33]([CH3:35])([CH3:34])[CH2:32][CH2:31][CH2:30][C:29]=1[CH3:36])=[CH:15]\[C:14]([OH:38])=[O:13]

Participants

3

Reactant 2

HCID 196092462-Bromocyclohept-1-ene-1-carbaldehydeHCID 86754815HCID 86754815, compound

Product 1

HCID 9841547HCID 9841547, compound

Procedure

As in Examples 4 and 5, 1-bromocycloheptene-2-carboxaldehyde was converted to (2E,4E)-3-Methyl-5-(2-((E)-2(2,6,6-trimethyl-1-cyclohexen-1-yl)ethenyl)-1-cyclohepten-1-yl)-2,4-pentadienoic acid ethyl ester which gave (2E,4E)-3-Methyl-5-(2-((E)-2(2,6,6-trimethyl-1-cyclohexen-1-yl)ethenyl)-1-cyclohepten-1-yl)-2,4-pentadienoic acid after hydrolysis with base.

Sources & evidence

ORD record
ord-18607097e7464b79b33aebc08f8b7641
Source dataset
uspto-grants-1999_11
Patent number
US05986131

Reaction notes

Loading…