HCID 15289119, compound → HCID 15289108, compound

HRID 1603694Notes

Reaction equation

HRID 1603694 reaction equation
[NH2:1][C:2]12[CH2:12][CH2:11][CH:8]([CH:9]=[CH:10]1)[CH:7]1[CH:3]2[C:4](=O)[NH:5][C:6]1=O.[H-].[H-].[H-].[H-].[Li+].[Al+3]>O1CCOCC1>[NH2:1][C:2]12[CH2:12][CH2:11][CH:8]([CH:9]=[CH:10]1)[CH:7]1[CH:3]2[CH2:4][NH:5][CH2:6]1

Participants

4

Reactant 2

HCID 15289119HCID 15289119, compoundHCID 21226445Aluminium lithium hydride

Product 1

HCID 15289108HCID 15289108, compound

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

45 g (0.234 mol) of 1-amino-4-azatricyclo[5.2.2.02,6 ]undec-8-ene-3,5-dione are reduced with 24 g of LiAlH4 in 500 ml of absolute dioxane as under Z 1-B and the mixture is worked up accordingly.

Sources & evidence

ORD record
ord-5f041309d54a4706b547db2e8e5b8797
Source dataset
uspto-grants-1999_11
Patent number
US05990122

Reaction notes

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