HCID 15289125, compound → HCID 15289126, compound

HRID 1603699Notes

Reaction equation

HRID 1603699 reaction equation
[NH2:1][C:2]12[CH2:12][CH2:11][CH:8]([CH:9]=[CH:10]1)[CH:7]1[CH:3]2[C:4](=O)[N:5]([CH2:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[C:6]1=O.[H-].[H-].[H-].[H-].[Li+].[Al+3]>>[NH2:1][C:2]12[CH2:12][CH2:11][CH:8]([CH:9]=[CH:10]1)[CH:7]1[CH:3]2[CH2:4][N:5]([CH2:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[CH2:6]1

Participants

3

Reactant 2

HCID 15289125HCID 15289125, compoundHCID 21226445Aluminium lithium hydride

Product 1

HCID 15289126HCID 15289126, compound

Procedure

19.3 g (68.2 mmol) of 1-amino-4-benzyl-4-azatricyclo[5.2.2.02,6 ]undec-8-ene-3,5-dione are reduced with 8 g of LiAlH4 as described under Z 1-B and the mixture is worked up accordingly.

Sources & evidence

ORD record
ord-dc69234373784443a8acefa682ba1fea
Source dataset
uspto-grants-1999_11
Patent number
US05990122

Reaction notes

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