HCID 53865090, compound → HCID 53744511, compound

HRID 1603952Notes

Reaction equation

HRID 1603952 reaction equation
[CH2:1]([CH:3]([O:7][C:8]1[CH:13]=[CH:12][C:11]([N+:14]([O-])=O)=[CH:10][C:9]=1[O:17][CH3:18])[C:4]([OH:6])=[O:5])[CH3:2]>CCO.[Pd]>[CH2:1]([CH:3]([O:7][C:8]1[CH:13]=[CH:12][C:11]([NH2:14])=[CH:10][C:9]=1[O:17][CH3:18])[C:4]([OH:6])=[O:5])[CH3:2]

Participants

4

Reactant 1

HCID 53865090HCID 53865090, compound

Product 1

HCID 53744511HCID 53744511, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

A solution of 5-15 (0.7 g, 2.7 mmol) in EtOH (10 mL) was treated with 10% Pd/C (0.14 g) and hydrogenated at balloon pressure. The solution was filtered through Solka-Floc and evaporated to give 5-16 as a tan oil.

Workup

  1. filtrationThe solution was filtered through Solka-Floc
  2. customevaporated

Sources & evidence

ORD record
ord-534d47d21cde4e479f08c0e766920ef6
Source dataset
uspto-grants-1999_11
Patent number
US05990107

Reaction notes

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