HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1604755Generated: November 1, 2026
(1H,1H-Perfluoroethyl)(2H-perfluoroethyl)ether → HCID 11483415, compound
https://huagongshe.com/reaction/1604755
Participants
| Role | Name | HCID | Charge |
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| Reactant | (1H,1H-Perfluoroethyl)(2H-perfluoroethyl)ether | HCID 164596 | — |
| Catalyst | Nickel | HCID 935 | — |
| Product | HCID 11483415 | HCID 11483415 | 46.4% |
Reaction Steps
CF3CH2OCF2CF2H (60 g, 0.3 mol), SbF5 (10 g, 0.045 mol) and TFE (20 g, 0.2 mol) were charged into a 400 mL Hastelloy™ nickel alloy tube and agitated at 25° C. for 12 hours. Fractionation of the liquid product gave CF3CH2OCF(C2F5)CF2H, 42 g (46.4% yield), b.p. 65.2-65.8° C. (see Table 1). No formation of PTFE was observed.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US05994599 |
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| Source dataset | uspto-grants-1999_11 |
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| ORD ID | ord-b3991ca622ac454b8bf86857c6bb372f |
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| Source note | uspto-grants-1999_11 |
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