HRID1604793

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：COC(=O)c1cc([N+](=O)[O-])ccc1-c1cc(OC)ccc1OC

HCID10805422

未命名化合物

结构：COc1ccc(F)cc1-c1ccc([N+](=O)[O-])cc1C(=O)O

HCID23433602

未命名化合物

PRODUCTS

生成物

结构：COc1ccccc1-c1cc(OC)c([N+](=O)[O-])cc1C(=O)O

HCID19604448

未命名化合物

收率 99%

PROCEDURE

实验过程

This compound was prepared in a manner similar to that of 5'-fluoro-2'-methoxy-4-nitro-2-biphenylcarboxylic acid (EXAMPLE 107) from methyl 2',5'-dimethoxy-4-nitro-2-biphenylcarboxylate (2.07 g) to afford 1.93 g (99%) of 2',5-dimethoxy-4-nitro-2-biphenylcarboxylic acid as a white solid. Data for 2', 5'-dimethoxy-4-nitro-2-biphenylcarboxylic acid: 1H NMR (400 MHz, acetone-d6) 8.64 (d, J=2.5, 1H), 8.43 (dd, J=8.4, 2.6, 1H), 7.67 (d, J=8.5, 1H), 6.94 (m, 2H), 3.80 (s, 3H), 3.68 (s, 3H).