Oxygen → HCID 21548938, compound

HRID 1605050Notes

Reaction equation

HRID 1605050 reaction equation
Br[CH2:2][CH:3]([C:5]1[CH:18]=[CH:17][C:16]2[O:15][C:14]3[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=3)[CH2:8][C:7]=2[CH:6]=1)[CH3:4].[O:19]=O.[NH4+].[Cl-]>CCOCC>[CH:6]1[C:7]2[CH2:8][C:9]3[C:14](=[CH:13][CH:12]=[CH:11][CH:10]=3)[O:15][C:16]=2[CH:17]=[CH:18][C:5]=1[CH:3]([CH3:4])[CH2:2][OH:19]

Participants

5

Reactant 3

HCID 977OxygenHCID 25517Ammonium ChlorideHCID 21548920HCID 21548920, compound

Product 1

HCID 21548938HCID 21548938, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

3.03 g. of 2-(1-bromo-2-propyl)-xanthene is reacted with 0.26 g. of Mg filings in 100 ml. of ether. The mixture is cooled to -5°, oxygen is introduced for 4 hours, and the mixture is combined with aqueous NH4Cl solution. The usual working-up step yields 2-(2-xanthenyl)-propanol, m.p. 86°-89°.

Workup

  1. temperatureThe mixture is cooled to -5°

Sources & evidence

ORD record
ord-b97da98f5c344661b834c634f5dd4c33
Source dataset
uspto-grants-1976_04
Patent number
US03948949

Reaction notes

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