HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl 4-oxocyclohexanecarboxylate → Ethyl 9-benzoyl-1,2,3,4-tetrahydrocarbazole-3-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl 4-oxocyclohexanecarboxylate | HCID 317638 | — |
| Reactant | 1-Benzoyl-1-phenylhydrazine hydrochloride | HCID 12197222 | — |
| Product | Ethyl 9-benzoyl-1,2,3,4-tetrahydrocarbazole-3-carboxylate | HCID 21548423 | — |
Reaction Steps
Following a procedure similar to that of Example 31 and using 11 g. of 1-benzoyl-1-phenylhydrazine hydrochloride and 7.62 g. of ethyl cyclohexanone-4-carboxylate (prepared in situ from the corresponding ethylene ketal) there was obtained 6.2 g. of the title compound; m.p. 67°-69°C. (ether-pentane).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03948939 |
| Source dataset | uspto-grants-1976_04 |
| ORD ID | ord-c9d94c7cae9a4c4aa012fe8cf7df77a2 |
| Source note | uspto-grants-1976_04 |