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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1605085Generated: October 30, 2026

Ethyl 4-oxocyclohexanecarboxylate → Ethyl 9-benzoyl-1,2,3,4-tetrahydrocarbazole-3-carboxylate

https://huagongshe.com/reaction/1605085

Reaction equation

Participants

RoleNameHCIDCharge
ReactantEthyl 4-oxocyclohexanecarboxylateHCID 317638—
Reactant1-Benzoyl-1-phenylhydrazine hydrochlorideHCID 12197222—
ProductEthyl 9-benzoyl-1,2,3,4-tetrahydrocarbazole-3-carboxylateHCID 21548423—

Reaction Steps

Following a procedure similar to that of Example 31 and using 11 g. of 1-benzoyl-1-phenylhydrazine hydrochloride and 7.62 g. of ethyl cyclohexanone-4-carboxylate (prepared in situ from the corresponding ethylene ketal) there was obtained 6.2 g. of the title compound; m.p. 67°-69°C. (ether-pentane).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS03948939
Source datasetuspto-grants-1976_04
ORD IDord-c9d94c7cae9a4c4aa012fe8cf7df77a2
Source noteuspto-grants-1976_04