HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Carbonate → HCID 12228978, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Carbonate | HCID 10340 | — |
| Reactant | Benzo-1,3-dioxole-5-methylamine | HCID 75799 | — |
| Reactant | Acetonitrile, [(4-chloro-6-phenyl-2-pyrimidinyl)thio]- | HCID 12228973 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 12228978 | HCID 12228978 | 57.4% |
Reaction Steps
A stirred suspension of 19.5 g (0.075 mole) of (4-chloro-6-phenyl-2-pyrimidinylthio)acetonitrile, 11.3 g (0.074 mole) of piperonylamine and 7.95 g (0.075 mole) of sodium carbonate was heated under reflux in 250 ml of ethanol for six hours. The mixture was filtered and the filtrate was cooled in ice. The precipitate was collected and recrystallized from ethanol to give 16 g of product, mp. 140°-142°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03950339 |
| Source dataset | uspto-grants-1976_04 |
| ORD ID | ord-274d444d5c164d119ebc61609f527d7d |
| Source note | uspto-grants-1976_04 |