Ammonia → HCID 178511262, compound

HRID 1605533Notes

Reaction equation

HRID 1605533 reaction equation
O.N.N.[C:4]([C@H:6]1[CH2:11][CH2:10][C@H:9]([C:12]([OH:14])=[O:13])[CH2:8][CH2:7]1)#[N:5]>[Co]>[NH2:5][CH2:4][C@H:6]1[CH2:7][CH2:8][C@H:9]([C:12]([OH:14])=[O:13])[CH2:10][CH2:11]1

Participants

5

Reactant 3

HCID 222AmmoniaHCID 12896473Azane;hydrateHCID 178511260HCID 178511260, compound

Product 1

HCID 178511262HCID 178511262, compound

Reagents, catalysts & solvents 1

HCID 104730CobaltCatalyst

Procedure

In 75 ml of ammonia water containing 0.033 mole of ammonia, 5 g. of trans-4-cyanocyclohexane-1-carboxylic acid was dissolved. To this solution, 0.5 g of Raney cobalt developed by a known method was added. The mixture was subjected to the same reaction and treatment as described in Example 1, and 4 g. of trans-4-aminomethylcyclohexane-1-carboxylic acid was obtained.

Workup

  1. additionwas added
  2. customThe mixture was subjected to the same reaction and treatment

Sources & evidence

ORD record
ord-6f389d80765941f2b82ff2d45da3dd0e
Source dataset
uspto-grants-1976_04
Patent number
US03950405

Reaction notes

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