3-Benzyloxy-5-nitro-4-phenylbenzoic acid → HCID 54117278, compound

HRID 1605557Notes

Reaction equation

HRID 1605557 reaction equation
[CH2:1]([O:8][C:9]1[CH:10]=[C:11]([CH:15]=[C:16]([N+:24]([O-])=O)[C:17]=1[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[C:12]([OH:14])=[O:13])[C:2]1C=C[CH:5]=[CH:4][CH:3]=1.[N+](C1C(C2C=CC=CC=2)=C(OCCCCC)C=C(C=1)C(O)=O)([O-])=O>>[NH2:24][C:16]1[C:17]([C:18]2[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=2)=[C:9]([O:8][CH2:1][CH2:2][CH2:3][CH2:4][CH3:5])[CH:10]=[C:11]([CH:15]=1)[C:12]([OH:14])=[O:13]

Participants

3

Reactant 2

HCID 215468443-Benzyloxy-5-nitro-4-phenylbenzoic acidHCID 21546877HCID 21546877, compound

Product 1

HCID 54117278HCID 54117278, compound

Procedure

By replacing in Example 2, step D, 3-benzyloxy-5-nitro-4-phenylbenzoic acid with 5-nitro-3-n-pentyloxy-4-phenylbenzoic acid, and following the procedure described, 5-amino-3-n-pentyloxy-4-phenylbenzoic acid is obtained crystallizing with 0.25 mole of water with a melting point of 134°-135° C.

Sources & evidence

ORD record
ord-a64f376eb45440acbcfbe58b6a54e7a4
Source dataset
uspto-grants-1976_04
Patent number
US03950380

Reaction notes

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