3-Benzyloxy-5-nitro-4-phenylbenzoic acid → HCID 178439326, compound

HRID 1605563Notes

Reaction equation

HRID 1605563 reaction equation
C(OC1C=C(C=C([N+]([O-])=O)C=1C1C=CC=CC=1)C(O)=O)C1C=CC=CC=1.[N+:27]([C:30]1[C:31]([C:42]2[CH:47]=[CH:46][CH:45]=[CH:44][CH:43]=2)=[C:32]([CH2:39][CH2:40][CH3:41])[CH:33]=[C:34]([CH:38]=1)[C:35]([OH:37])=[S:36])([O-])=O>>[NH2:27][C:30]1[C:31]([C:42]2[CH:47]=[CH:46][CH:45]=[CH:44][CH:43]=2)=[C:32]([CH2:39][CH2:40][CH3:41])[CH:33]=[C:34]([CH:38]=1)[C:35]([OH:37])=[S:36]

Participants

3

Reactant 2

HCID 215468443-Benzyloxy-5-nitro-4-phenylbenzoic acidHCID 178439327HCID 178439327, compound

Product 1

HCID 178439326HCID 178439326, compound

Procedure

By replacing in Example 2, step D, 3-benzyloxy-5-nitro-4-phenylbenzoic acid with 5-nitro-4-phenyl-3-n-propylthiobenzoic acid, and following the procedure described, 5-amino-4-phenyl-3-n-propylthiobenzoic acid is obtained with a melting point of 190°-191° C.

Sources & evidence

ORD record
ord-babdc40cf5404a33bf5395def4ead7a2
Source dataset
uspto-grants-1976_04
Patent number
US03950380

Reaction notes

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