Bromine → 2-Amino-3-bromo-N,N-dimethyl-5-methoxy-benzylamine

HRID 1605595Notes

Reaction equation

HRID 1605595 reaction equation
[NH2:1][C:2]1[CH:11]=[CH:10][C:9]([O:12][CH3:13])=[CH:8][C:3]=1[CH2:4][N:5]([CH3:7])[CH3:6].[Br:14]Br>C(Cl)Cl>[NH2:1][C:2]1[C:11]([Br:14])=[CH:10][C:9]([O:12][CH3:13])=[CH:8][C:3]=1[CH2:4][N:5]([CH3:7])[CH3:6]

Participants

4

Reactant 2

HCID 24408BromineHCID 203190282-Amino-N,N-dimethyl-5-methoxy-benzylamine

Product 1

HCID 203190152-Amino-3-bromo-N,N-dimethyl-5-methoxy-benzylamine

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

2-Amino-3-bromo-N,N-dimethyl-5-methoxy-benzylamine was prepared from 2-amino-N,N-dimethyl-5-methoxy-benzylamine and bromine analogous to Example 9. Proof of structure by IR-, UV- and NMR-spectra. IR-spectrum (methylenechloride): 3250 cm-1NH2 ; 3410 cm-1NH2 ; 2780 cm-1N(CH3)2 ; 2830 cm-1OCH3 ; 1590 cm-1C=C; 1600 cm-1C=C.

Sources & evidence

ORD record
ord-858fb91bac2047cab0b8b7f8a7bb5bc6
Source dataset
uspto-grants-1976_04
Patent number
US03950393

Reaction notes

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