HuagongsheHuagongshe Chemistry Print Report · For research reference only
p-Toluenesulfonic acid → HCID 20367180, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | p-Toluenesulfonic acid | HCID 6101 | — |
| Reactant | beta-Aminobeta-ethoxyacrylic acid ethyl ester | HCID 278451 | — |
| Reactant | [(2,5-Dimethylphenyl)methyl]hydrazine | HCID 20367329 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 20367180 | HCID 20367180 | — |
Reaction Steps
26.6 g of 2,5-dimethylbenzylhydrazine were added dropwise to a solution of 28.2 g of β-amino-β-ethoxyacrylic acid ethyl ester and 1 g of p-toluenesulphonic acid in 130 ml of ethanol, in the course of which the temperature rose from 25 to 35°C. After stirring overnight, the compound identified above separated out, and was filtered off and recrystallised from ethanol. Melting point: 124°, 20 g (52%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03950528 |
| Source dataset | uspto-grants-1976_04 |
| ORD ID | ord-eef80e95ff5d48638b06f977f7194952 |
| Source note | uspto-grants-1976_04 |