Hexadec-1-ene-1-sulfonic acid → 1-Hexadecene

HRID 1605806Notes

Reaction equation

HRID 1605806 reaction equation
[CH:1](S(O)(=O)=O)=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]>CC(C)=O>[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Participants

3

Reactant 1

HCID 107566Hexadec-1-ene-1-sulfonic acid

Product 1

HCID 123951-Hexadecene

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

The aqueous-acetone layer which contained the sulfonic acid fraction of the product was stripped of solvents at 40°-45°C. under a vacuum to give 2.85 g. of viscous acid identified as hexadecene sulfonic acid on the basis of an IR spectrum which showed the presence of trans olefinic double bond (965 cm-1) and the absence of sultones (no 830 and 530 cm-1 bands).

Workup

  1. customwas stripped of solvents at 40°-45°C. under a vacuum
  2. customto give 2.85 g

Sources & evidence

ORD record
ord-47b3cf032cd04a88af3fdbac6b14dce9
Source dataset
uspto-grants-1976_04
Patent number
US03951823

Reaction notes

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