Methanethiol → 2-Pyrazinyl-ethyl methyl sulfide

HRID 1606199Notes

Reaction equation

HRID 1606199 reaction equation
[CH:1]([C:3]1[CH:8]=[N:7][CH:6]=[CH:5][N:4]=1)=[CH2:2].[CH3:9][SH:10].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>>[CH3:9][S:10][CH2:2][CH2:1][C:3]1[CH:8]=[N:7][CH:6]=[CH:5][N:4]=1

Participants

4

Reactant 3

HCID 878MethanethiolHCID 7187Benzoyl PeroxideHCID 77840Vinylpyrazine

Product 1

HCID 226304002-Pyrazinyl-ethyl methyl sulfide

Procedure

1h. 2-Pyrazinyl-ethyl methyl sulfide was prepared by reacting vinylpyrazine [c.f. J.Org.Chem. 27, 1363 (1962)] with methylmercaptan by the action of ultra violet light and in the presence of benzoyl peroxide by the method described in Acta Chem. Scand. 8, 295 (1954). The product was identified by mass spectrometry. It has a b.p. of 57°-69°C. at 0.05 mm. Hg.

Workup

  1. custom1h

Sources & evidence

ORD record
ord-51c203c73b8844a58edf15aaabebb00a
Source dataset
uspto-grants-1976_04
Patent number
US03952024

Reaction notes

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