HCID 53966083, compound → HCID 21544428, compound

HRID 1606713Notes

Reaction equation

HRID 1606713 reaction equation
[CH2:1]([CH:3]([OH:16])[C:4]1[CH:9]=[CH:8][C:7]([CH:10]([OH:15])[C:11]([CH3:14])([CH3:13])[CH3:12])=[CH:6][CH:5]=1)C.[CH3:17][CH:18]([OH:32])[C:19]1[CH:24]=[CH:23][C:22]([CH:25]([OH:30])[C:26]([CH3:29])([CH3:28])[CH3:27])=[CH:21][C:20]=1[Cl:31].CC(O)C1C=C[C:38]([CH:41]([OH:46])C(C)(C)C)=CC=1>>[Cl:31][C:20]1[CH:21]=[C:22]([CH:25]([O:30][C:10](=[O:15])[CH3:7])[C:26]([CH3:27])([CH3:28])[CH3:29])[CH:23]=[CH:24][C:19]=1[CH:18]([O:32][C:41](=[O:46])[CH3:38])[CH3:17].[C:25]([O:15][CH:10]([C:7]1[CH:6]=[CH:5][C:4]([CH:3]([O:16][C:41](=[O:46])[CH3:38])[CH3:1])=[CH:9][CH:8]=1)[C:11]([CH3:12])([CH3:13])[CH3:14])(=[O:30])[CH3:22]

Participants

5

Reactant 3

HCID 53966083HCID 53966083, compoundHCID 54214639HCID 54214639, compoundHCID 54375631HCID 54375631, compound

Product 2

HCID 21544428HCID 21544428, compoundHCID 21544429HCID 21544429, compound

Procedure

When the above reaction is carried out using in place of α-ethyl-4-(2,2-dimethyl-1-hydroxypropyl)benzyl alcohol an equivalent amount of α-methyl-2-chloro-4-(2,2-dimethyl-1-hydroxypropyl)benzyl alcohol or α-methyl-4-(2,2-dimethyl-1-hydroxypropyl)benzyl alcohol, there is obtained 1-[2-chloro-4-(1-acetoxy-2,2-dimethylpropyl)phenyl]-1-acetoxyethane or 1-[4-(1-acetoxy- 2,2-dimethylpropyl)phenyl]-1-acetoxy ethane.

Workup

  1. customWhen the above reaction

Sources & evidence

ORD record
ord-69f1e7a622004c7089093f05c3da097d
Source dataset
uspto-grants-1976_04
Patent number
US03953525

Reaction notes

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