Ethanolamine → HCID 19851165, compound

HRID 1606862Notes

Reaction equation

HRID 1606862 reaction equation
[NH2:1][C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[C:4](Cl)[C:3]=1[N+:10]([O-:12])=[O:11].[CH2:13]([CH2:15][NH2:16])[OH:14]>>[NH2:1][C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[C:4]([NH:16][CH2:15][CH2:13][OH:14])[C:3]=1[N+:10]([O-:12])=[O:11]

Participants

3

Reactant 2

HCID 700EthanolamineHCID 4643061HCID 4643061, compound

Product 1

HCID 19851165HCID 19851165, compound

Procedure

0.05 mole (11.2 g) of 2-amino-4,6-dichloronitrobenzene (Recueil. Trav. Chim. 68, p. 88 [1949]) in 45 ml of ethanolamine was heated for 2 hours over a boiling water bath. The reaction medium was diluted with 150 ml of ice water. After acidification with 80 ml of hydrochloric acid, the desired product precipitated out. It melted at 183° C. after recrystallization from 400 ml isopropanol.

Workup

  1. customAfter acidification with 80 ml of hydrochloric acid, the desired product precipitated out
  2. customIt melted at 183° C. after recrystallization from 400 ml isopropanol

Sources & evidence

ORD record
ord-2cc9d1eb26d24380b6b902fbe7ad1805
Source dataset
uspto-grants-1989_09
Patent number
US04863482

Reaction notes

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