HCID 19851984, compound → HCID 19851955, compound

HRID 1607145Notes

Reaction equation

HRID 1607145 reaction equation
[C:1]([C:4]1[CH:23]=[CH:22][C:7]([O:8][CH2:9][CH2:10][CH2:11][O:12][C:13]2[CH:14]=[C:15]([N+:19]([O-])=O)[CH:16]=[CH:17][CH:18]=2)=[C:6]([CH2:24][CH2:25][CH3:26])[C:5]=1[OH:27])(=[O:3])[CH3:2].[C:28]([C:31]1[CH:52]=[CH:51][C:34]([O:35][CH2:36][CH2:37][CH2:38][O:39][C:40]2[CH:41]=[C:42]([N+:48]([O-])=O)[CH:43]=[CH:44][C:45]=2[C:46]#[N:47])=[C:33]([CH2:53][CH2:54][CH3:55])[C:32]=1[OH:56])(=[O:30])[CH3:29]>>[C:1]([C:4]1[CH:23]=[CH:22][C:7]([O:8][CH2:9][CH2:10][CH2:11][O:12][C:13]2[CH:14]=[C:15]([CH:16]=[CH:17][CH:18]=2)[NH2:19])=[C:6]([CH2:24][CH2:25][CH3:26])[C:5]=1[OH:27])(=[O:3])[CH3:2].[C:28]([C:31]1[CH:52]=[CH:51][C:34]([O:35][CH2:36][CH2:37][CH2:38][O:39][C:40]2[CH:41]=[C:42]([CH:43]=[CH:44][C:45]=2[C:46]#[N:47])[NH2:48])=[C:33]([CH2:53][CH2:54][CH3:55])[C:32]=1[OH:56])(=[O:30])[CH3:29]

Participants

4

Reactant 2

HCID 19851984HCID 19851984, compoundHCID 19851995HCID 19851995, compound

Product 2

HCID 19851955HCID 19851955, compoundHCID 19851974HCID 19851974, compound

Procedure

In analogous manner, starting from 3-[3-(4-acetyl-3-hydroxy-2-n-propylphenoxy)-propoxy]-nitrobenzene and from 3-[3-(4-acetyl-3-hydroxy-2-n-propylphenoxy)-propyloxy]-4-cyano-nitrobenzene, there are obtained 3-[3-(4-acetyl-3-hydroxy-2-n-propylphenoxy)-propoxy]-aniline having a melting point of 76°-77° (ether/petroleum ether) and 3-[3-(4-acetyl-3-hydroxy-2-n-propylphenoxy)-propyloxy]-4-cyano-aniline.

Sources & evidence

ORD record
ord-713e780fc3e44d60940cbc4cbed22ec2
Source dataset
uspto-grants-1989_09
Patent number
US04863942

Reaction notes

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