HCID 522362, compound → (-)-Asparagine

HRID 1607314Notes

Reaction equation

HRID 1607314 reaction equation
[NH2:1][CH:2]([C:7]([OH:9])=[O:8])[CH2:3][C:4](=[O:6])[NH2:5].O>O>[NH2:1][C@H:2]([C:7]([OH:9])=[O:8])[CH2:3][C:4](=[O:6])[NH2:5]

Participants

3

Reactant 1

HCID 522362HCID 522362, compound

Product 1

HCID 6267(-)-Asparagine

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

H2O: A slurry of D,L-Asn.H2O (500 mg) and poly-(Nε -methacryloyl-L-lysine) in water (5 ml) was heated to about 80° C. until complete dissolution occurred. The warm solution was filtered and cooled to room temperature without agitation. After 20 h the separated crystals were recovered by filtration and the enantiomeric excess was determined. The conditions and results are summarized in Table III.

Workup

  1. filtrationThe warm solution was filtered
  2. filtrationAfter 20 h the separated crystals were recovered by filtration
  3. customThe conditions and results

Sources & evidence

ORD record
ord-b979ab3ad6ac4fe4be5e26442b904009
Source dataset
uspto-grants-1989_09
Patent number
US04864031

Reaction notes

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