HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tributylstannane → HCID 23052446, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tributylstannane | HCID 5948 | — |
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | HCID 23052449 | HCID 23052449 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 23052446 | HCID 23052446 | — |
Reaction Steps
To a solution of 43 (24 g, 0.105 mol) in toluene (400 ml) was added azobisisobutyronitrile (6 g) and tri-n-butyltin hydride (90 g). The mixture was refluxed overnight and then evaporated in vacuo. Elution from a column of silica gel with ethyl acetate-heptane (1:2) gave the title compound as an oil. Yield: 10.4 g (0.0538 mol, 51%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04866077 |
| Source dataset | uspto-grants-1989_09 |
| ORD ID | ord-789a7820ccab4a0c93936a3dbbf0ed7f |
| Source note | uspto-grants-1989_09 |