HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Hydroxyacetyl-5-(benzyloxy)indole → 3-Glyoxalyl-5-(benzyloxy)indole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Hydroxyacetyl-5-(benzyloxy)indole | HCID 14168303 | — |
| Catalyst | Cupric acetate monohydrate | HCID 165397 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 3-Glyoxalyl-5-(benzyloxy)indole | HCID 14168304 | — |
Reaction Steps
A solution of 20 in ethanol was treated with copper(II) acetate monohydrate in 50% aqueous acetic acid as described above for 15. Work-up gave nearly pure 3-glyoxalyl-5-(benzyloxy)indole 21.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04866084 |
| Source dataset | uspto-grants-1989_09 |
| ORD ID | ord-d0acd63e38724b65b9cfcf0f86105429 |
| Source note | uspto-grants-1989_09 |