Dipotassium tetrachloroplatinate → Platinous chloride

HRID 1607618Notes

Reaction equation

HRID 1607618 reaction equation
Cl.Cl.[C:3]1([CH2:9][NH2:10])([CH2:7][NH2:8])[CH2:6][CH2:5][CH2:4]1.C([O-])(=O)C.[Na+].[Cl:16][Pt-2:17](Cl)(Cl)[Cl:18].[K+].[K+]>O>[C:3]1([CH2:9][NH2:10])([CH2:7][NH2:8])[CH2:6][CH2:5][CH2:4]1.[Pt:17]([Cl:18])[Cl:16]

Participants

6

Reactant 3

HCID 61440Dipotassium tetrachloroplatinateHCID 517045Sodium AcetateHCID 202036281,1-Bis(aminomethyl)cyclobutane dihydrochloride

Product 2

HCID 2770Platinous chlorideHCID 4328361,1-Cyclobutanedimethanamine

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A solution of 1.87 g of the above amine in 30 ml of water was treated with 1.64 g of solid sodium acetate followed by 4.15 g of potassium tetrachloroplatinate. The mixture was stirred overnight and filtered. The filtrate was concentrated, giving as a solid 1,1-cyclobutanedimethanamine, compound with platinum chloride.

Workup

  1. filtrationfiltered
  2. concentrationThe filtrate was concentrated

Sources & evidence

ORD record
ord-91ffd4cfe23c49ff84a538493da4e516
Source dataset
uspto-grants-1989_09
Patent number
US04866092

Reaction notes

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