Sodium Carbonate → HCID 14818208, compound

Participants

Reaction Steps

A mixture of 28 g 1-(3'-bromo-4'-acetoxy-5'-methylphenyl)ethanol and 0.5 g freshly prepared potassium hydrogen sulfate is heated under a 20 Torr vacuum to 190°-200° C. The distillate is transferred to an ice-filled reaction vessel which contains 2 g t-butylhydroquinone. After 2h, the distillate is taken up in ether, the ether phases are treated with a5% sodium carbonate solution and dried, then the solvent is distilled off under vacuum. At 0.05 Torr, 6.8 g of an impure product is obtained at a temperature of 86°to 89° C., from which 18 g of pure monomercan be obtained.

Provenance & Evidence