Methyl (o-nitrobenzylthio)-acetate → HCID 43617941, compound

HRID 1608140Notes

Reaction equation

HRID 1608140 reaction equation
[N+:1]([C:4]1[CH:16]=[CH:15][CH:14]=[CH:13][C:5]=1[CH2:6][S:7][CH2:8][C:9]([O:11][CH3:12])=[O:10])([O-])=O.[H][H]>C(O)C.[Ni]>[NH2:1][C:4]1[CH:16]=[CH:15][CH:14]=[CH:13][C:5]=1[CH2:6][S:7][CH2:8][C:9]([O:11][CH3:12])=[O:10]

Participants

5

Reactant 2

HCID 12136843Methyl (o-nitrobenzylthio)-acetateHCID 178418361HCID 178418361, compound

Product 1

HCID 43617941HCID 43617941, compound

Reagents, catalysts & solvents 2

HCID 935NickelCatalystHCID 702EthanolSolvent

Procedure

Methyl (o-nitrobenzylthio)-acetate (24.4 g) was dissolved in ethanol (500 ml). Raney nickel was added and the mixture was hydrogenated at room temperature and 1 atm. of hydrogen pressure. The title compound was obtained as an oil after filtration and evaporation of the reaction mixture.

Workup

  1. customwas hydrogenated at room temperature

Sources & evidence

ORD record
ord-0a6e2e73c4054db0b18e2a93ff85868a
Source dataset
uspto-grants-1989_09
Patent number
US04870073

Reaction notes

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