N,N-Diethyl-1,3-propanediamine → HCID 14723690, compound

HRID 1608302Notes

Reaction equation

HRID 1608302 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([C:10]2[CH:11]=[N:12][N:13]([CH2:21][C:22]([O:24]CC)=O)[C:14]=2[C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[CH:6][CH:5]=1)([O-:3])=[O:2].[CH2:27]([N:29]([CH2:34][CH3:35])[CH2:30][CH2:31][CH2:32][NH2:33])[CH3:28]>>[CH2:27]([N:29]([CH2:34][CH3:35])[CH2:30][CH2:31][CH2:32][NH:33][C:22](=[O:24])[CH2:21][N:13]1[C:14]([C:15]2[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=2)=[C:10]([C:7]2[CH:8]=[CH:9][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][CH:6]=2)[CH:11]=[N:12]1)[CH3:28]

Participants

3

Reactant 2

HCID 61011N,N-Diethyl-1,3-propanediamineHCID 14723682HCID 14723682, compound

Product 1

HCID 14723690HCID 14723690, compound

Procedure

A solution of 3.51 g (0.01 mol) of ethyl 4-(4-nitrophenyl)-5-phenyl-1H-pyrazole-1-acetate of example 8 in 10 mL of 3(diethylamino)propanamine was reacted as in example 44. The product was recrystallized from methyl t-butyl ether to yield 5.4 g, mp 100°-101° C.

Workup

  1. customThe product was recrystallized from methyl t-butyl ether
  2. customto yield 5.4 g, mp 100°-101° C.

Sources & evidence

ORD record
ord-14333eb882eb422a816087b1e7edeb93
Source dataset
uspto-grants-1989_09
Patent number
US04870095

Reaction notes

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