(phenylsulfonyl)acetic acid → HCID 20086070, compound

HRID 1608474Notes

Reaction equation

HRID 1608474 reaction equation
[C:1]1([S:7]([CH2:10][C:11]([OH:13])=[O:12])(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(=O)(O)O.[NH2:18][C:19]([NH2:21])=[NH:20]>>[C:1]1([S:7]([CH2:10][C:11]([O-:13])=[O:12])(=[O:9])=[O:8])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1.[NH2:20][C:19]([NH2:21])=[NH2+:18]

Participants

3

Reactant 2

HCID 59543(phenylsulfonyl)acetic acidHCID 286947Carbonic acid-guanidine (1:1)

Product 1

HCID 20086070HCID 20086070, compound

Procedure

Guanidinium phenylsulfonylacetate (Compound C14-A5) was prepared in an analagous manner from 2.310 g (0.01154 mol) of phenylsulfonylacetic acid and 1.039 g (0.005769 mol) of guanidine carbonate to afford 2.052 g of product; mp 137°-139° C. (dec). NMR was in agreement with the proposed structure.

Sources & evidence

ORD record
ord-fbb96d841a2242ee90a8d7a98de5ae76
Source dataset
uspto-grants-1995_03
Patent number
US05395747

Reaction notes

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