HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1608692Generated: October 30, 2026
Carbon Tetrachloride → HCID 20087058, compound
https://huagongshe.com/reaction/1608692
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Carbon Tetrachloride | HCID 5943 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | 35113-53-2 | HCID 386845 | — |
| Product | HCID 20087058 | HCID 20087058 | — |
Reaction Steps
A solution of 217 g 2-isopropyl-5-hydroxymethyl-1,3-dioxane in 11 of carbon tetrachloride is added dropwise to a solution of 356 g triphenylphosphine in 1 l of carbon tetrachloride, heated to 70° C. The mixture is refluxed and after approx. 1 hour cooled down (ice-bath), filtrated and evaporated. The residue is repeatedly treated with diethylether and filtered. After evaporating the filtrate the residue is purified by distillation. The desired 2-isopropyl-5-chloromethyl-1,3-dioxane is obtained as a colorless liquid; b.p. 84°-94° C. mm Hg; cis-trans mixture; identification by NMR.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US05395946 |
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| Source dataset | uspto-grants-1995_03 |
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| ORD ID | ord-3bdd933d53ad4c0aa4b03b827a227172 |
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| Source note | uspto-grants-1995_03 |
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