HCID 19035377, compound → HCID 10763262, compound

HRID 1608781Notes

Reaction equation

[C:1]([O:5][C:6]([N:8]1[CH2:13][CH2:12][CH:11]([CH2:14][CH2:15][C:16]2[S:20][C:19]3[S:21][C:22]([CH:24]=[O:25])=[CH:23][C:18]=3[CH:17]=2)[CH2:10][CH2:9]1)=[O:7])([CH3:4])([CH3:3])[CH3:2].[O-:26]Cl=O.[Na+]>>[C:1]([O:5][C:6]([N:8]1[CH2:9][CH2:10][CH:11]([CH2:14][CH2:15][C:16]2[S:20][C:19]3[S:21][C:22]([C:24]([OH:26])=[O:25])=[CH:23][C:18]=3[CH:17]=2)[CH2:12][CH2:13]1)=[O:7])([CH3:4])([CH3:2])[CH3:3]

Participants

Reactant 2

HCID 19035377HCID 19035377, compound

HCID 23668197Sodium Chlorite

Product 1

HCID 10763262HCID 10763262, compound

Procedure

3-3 (2.0 g, 5.27 mmol) was treated with NaClO2 (5.27 g, 58.3 mmol) as described for 1-7 to provide 3-4 as a white solid.

Sources & evidence

ORD record: ord-2aa125be1bba4873b4e163f581dd8f73
Source dataset: uspto-grants-1995_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05397791

Reaction notes

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