N,N-Dimethylbenzylamine → HCID 131718928, compound

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Reaction Steps

A mixture of 3.74 bis(trimethylsiloxy) methylsilylethyl benzyl chloride and 1.38 g of N,N-dimethylbenzylamine in isopropanol was treated at 80° C. for 4 hours and then evaporated in vacuo. The resulting glassy material was treated 5 times with n-hexane and then crystallized from ethyl acetate-n-hexane. A yield of 0.8 g (16%) of Compound [IG] was obtained. The structure of the compound was confirmed by elemental analysis, infrared spectroscopy, mass spectroscopy and nmr. The nmr data showed: 7.7-7.0 ppm (b,4 aromatic), 5.1 ppm (b,4,N--CH2), 3.1 ppm (s,6,N--CH3) and 0.0 ppm (s, 21 ,Si--CH3).

Provenance & Evidence