Perhydroxyl radical → 2,3-Dichloro-4,6-dinitrophenol

HRID 1609380Notes

Reaction equation

[Cl:1][C:2]1[CH:7]=[C:6]([N+:8]([O-:10])=[O:9])[CH:5]=[C:4]([N+:11]([O-:13])=[O:12])[C:3]=1[Cl:14].[O-:15]O>>[Cl:1][C:2]1[C:3]([Cl:14])=[C:4]([N+:11]([O-:13])=[O:12])[CH:5]=[C:6]([N+:8]([O-:10])=[O:9])[C:7]=1[OH:15]

Participants

Reactant 2

HCID 18500Perhydroxyl radical

HCID 110209011,2-Dichloro-3,5-dinitrobenzene

Product 1

HCID 108579782,3-Dichloro-4,6-dinitrophenol

Procedure

contacting 1,2-dichloro-3,5-dinitrobenzene with a hydroperoxide in the presence of anhydrous base to form 2,3-dichloro-4,6-dinitrophenol;

Sources & evidence

ORD record: ord-aa4c6427f9374a16a1f5f0fe6b3030fa
Source dataset: uspto-grants-1995_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05399768

Reaction notes

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