HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Iodide → Tert-butyl[(6-iodohexyl)oxy]dimethylsilane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Iodide | HCID 5238 | — |
| Reactant | [(6-Chlorohexyl)oxy](1,1-dimethylethyl)dimethylsilane | HCID 10083489 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | Tert-butyl[(6-iodohexyl)oxy]dimethylsilane | HCID 13972989 | — |
Reaction Steps
A solution of sodium iodide (13.5 g, 90 mmol) and 1-(tert-butyldimethylsilyloxy)-6-chloro-hexane (Preparation 20) (8.35 g, 22 mmol) in acetone (70 ml) was refluxed overnight. The reaction mixture was cooled to room temperature and filtered. The filtrate was worked-up (hexane) to give the desired compound as yellow oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05401732 |
| Source dataset | uspto-grants-1995_03 |
| ORD ID | ord-95e4696a421a497d915996c9261bd306 |
| Source note | uspto-grants-1995_03 |