HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → Methyl 3-hydroxy-2-methyl-5-nitro-3-indenylacetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Ethanol | HCID 702 | — |
| Reactant | 6-Methoxy-2-methyl-2,3-dihydro-1H-inden-1-one | HCID 231178 | — |
| Reactant | 2-Methyl-6-nitro-1-indanone | HCID 21840586 | — |
| Solvent | Water | HCID 962 | — |
| Product | Methyl 3-hydroxy-2-methyl-5-nitro-3-indenylacetate | HCID 53908697 | — |
Reaction Steps
The procedure of Example 1C is followed using 2-methyl-6-nitro indanone in equivalent quantities in place of 6-methoxy-2-methyl-indanone used therein. After the mixture is condensed, 30 ml. of ethanol and 50 ml. of acetic acid are added. The mixture is then poured into 700 ml. of water. Extraction with ether gives methyl 3-hydroxy-2-methyl-5-nitro-3-indenylacetate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05401774 |
| Source dataset | uspto-grants-1995_03 |
| ORD ID | ord-346e6d9c56484861aff068626ae5d916 |
| Source note | uspto-grants-1995_03 |