2-(((Trifluoromethyl)sulfonyl)oxy)acetic acid methyl ester → TfO-CH2COOnBu

HRID 1610813Notes

Reaction equation

HRID 1610813 reaction equation
[S:1]([O:8][CH2:9][C:10]([O:12][CH3:13])=[O:11])([C:4]([F:7])([F:6])[F:5])(=[O:3])=[O:2].[CH2:14]([CH:18](O)C([O-])=O)[CH2:15]CC>>[S:1]([O:8][CH2:9][C:10]([O:12][CH2:13][CH2:15][CH2:14][CH3:18])=[O:11])([C:4]([F:6])([F:7])[F:5])(=[O:3])=[O:2]

Participants

3

Reactant 2

HCID 112297732-(((Trifluoromethyl)sulfonyl)oxy)acetic acid methyl esterHCID 219248442-Hydroxyhexanoate

Product 1

HCID 121358209TfO-CH2COOnBu

Procedure

Prepared in the same way as described for TfO-CH2COOMe starting with butylglycolate.

Workup

  1. customPrepared in the same way

Sources & evidence

ORD record
ord-effa115c9837430e80abaf5cdab2669b
Source dataset
uspto-grants-2006_01
Patent number
US06984627B1

Reaction notes

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