Sodium Hydroxide → HCID 9933247, compound

HRID 1612011Notes

Reaction equation

HRID 1612011 reaction equation
[CH3:1][C:2]1([CH3:30])[CH2:11][CH2:10][C:9]([CH3:13])([CH3:12])[C:8]2[CH:7]=[C:6]([Se:14][C:15]3[CH:25]=[CH:24][C:18]([C:19]([O:21]CC)=[O:20])=[CH:17][N:16]=3)[C:5]([O:26][CH2:27][CH2:28][CH3:29])=[CH:4][C:3]1=2.[OH-].[Na+]>C(O)C>[CH3:1][C:2]1([CH3:30])[CH2:11][CH2:10][C:9]([CH3:12])([CH3:13])[C:8]2[CH:7]=[C:6]([Se:14][C:15]3[CH:25]=[CH:24][C:18]([C:19]([OH:21])=[O:20])=[CH:17][N:16]=3)[C:5]([O:26][CH2:27][CH2:28][CH3:29])=[CH:4][C:3]1=2

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 9847719HCID 9847719, compound

Product 1

HCID 9933247HCID 9933247, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

In a manner similar to that of Example 2, by reaction of 485 mg (1.02 mmol) of ethyl 6-(5,5,8,8-tetramethyl-3-propoxy-5,6,7,8-tetrahydro 2-naphthylselanyl)nicotinate with 385 mg (9.6 mmol) of sodium hydroxide in ethanol (20 ml), 444 mg (97%) of a white solid are obtained. m.p.: 220° C.

Workup

  1. customare obtained

Sources & evidence

ORD record
ord-9eaef11df86048ae967b43741d2d07c3
Source dataset
uspto-grants-2006_01
Patent number
US06992094B1

Reaction notes

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