Sodium Hydroxide → HCID 22252714, compound

HRID 1612025Notes

Reaction equation

HRID 1612025 reaction equation
C[O:2][C:3]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][O:12][C:13]1[C:14]([Se:27][C:28]2[CH:38]=[CH:37][C:31]([C:32]([O:34]CC)=[O:33])=[CH:30][CH:29]=2)=[CH:15][C:16]2[C:17]([CH3:26])([CH3:25])[CH2:18][CH2:19][C:20]([CH3:24])([CH3:23])[C:21]=2[CH:22]=1)=[O:4].[OH-].[Na+]>C1COCC1.C(O)C>[C:3]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][O:12][C:13]1[C:14]([Se:27][C:28]2[CH:38]=[CH:37][C:31]([C:32]([OH:34])=[O:33])=[CH:30][CH:29]=2)=[CH:15][C:16]2[C:17]([CH3:25])([CH3:26])[CH2:18][CH2:19][C:20]([CH3:24])([CH3:23])[C:21]=2[CH:22]=1)([OH:4])=[O:2]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 22252746HCID 22252746, compound

Product 1

HCID 22252714HCID 22252714, compound

Reagents, catalysts & solvents 1

HCID 21873804Tetrahydrofuran ethanolSolvent

Procedure

In a manner similar to that of Example 2, by reaction of 410 mg (0.7 mmol) of ethyl 4-[3-(7-methoxycarbonylheptyloxy)-5,5,8,8-tetramethyl5,6,7,8-tetrahydro-2-naphthylselanyl]benzoate with 280 mg (7 mmol) of sodium hydroxide in a THF/ethanol mixture (5 ml/5 ml), 326 mg (85%) of a white powder are obtained. m.p.: 183° C.

Workup

  1. customare obtained

Sources & evidence

ORD record
ord-bfc1f85e2c244c1698e6472e4f8fae71
Source dataset
uspto-grants-2006_01
Patent number
US06992094B1

Reaction notes

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