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HRID1612178

反应详情

EQUATION

反应方程式

HRID 1612178 的结构方程式

REACTANTS

反应物

2
结构：COc1cccc2c1CCCC2=O
HCID36620

1(2H)-Naphthalenone, 3,4-dihydro-5-methoxy-

C11H12O2

结构：NC1CCCc2occc21
HCID18525171

4,5,6,7-Tetrahydro-1-benzofuran-4-amine

C8H11NO

PRODUCTS

生成物

1
结构：COc1cccc2c1CCCC2N
HCID38899

5-Methoxy-1,2,3,4-tetrahydronaphthalen-1-amine

C11H15NO

PROCEDURE

实验过程

Following the procedure for the preparation of 4,5,6,7-tetrahydro-1-benzofuran-4-amine but substituting 5-methoxy-3,4-dihydronaphthalen-1(2H)-one and making non-critical variations provided the title compound as a oil: 1H NMR (400 MHz, CDCl3) δ 7.19, 7.05, 6.75, 4.00, 3.84, 2.76, 2.61, 1.97, 1.70; 13C NMR (100 MHz, CDCl3) δ 157.44, 142.83, 126.67, 126.02, 120.53, 108.09, 55.72, 49.75, 33.21, 23.57, 19.11; HRMS (FAB) calcd for C11H15NO+H 178.1232, found 178.1233.