HuagongsheHuagongshe Chemistry Print Report · For research reference only
6-Methoxy-alpha-tetralone → 6-Methoxy-1,2,3,4-tetrahydro-1-naphthalenylamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 6-Methoxy-alpha-tetralone | HCID 14112 | — |
| Reactant | 4,5,6,7-Tetrahydro-1-benzofuran-4-amine | HCID 18525171 | — |
| Product | 6-Methoxy-1,2,3,4-tetrahydro-1-naphthalenylamine | HCID 38250 | — |
Reaction Steps
Following the procedure for the preparation of 4,5,6,7-tetrahydro-1-benzofuran-4-amine but substituting 6-methoxy-3,4-dihydronaphthalen-1(2H)-one and making non-critical variations provided the title compound as a oil: 1H NMR (400 MHz, CDCl3) δ 7.34, 6.78, 6.63, 3.97, 3.79, 2.74, 1.77, 1.89; 13C NMR (100 MHz, CDCl3) δ 158.47, 138.45, 133.91, 129.64, 113.71, 112.67, 55.61, 49.23, 34.25, 30.31, 24.6, 23.23, 19.87.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06992087B2 |
| Source dataset | uspto-grants-2006_01 |
| ORD ID | ord-74afce31a319482f955871df0aba02d7 |
| Source note | uspto-grants-2006_01 |