5-Methoxyindan-1-one → 5-Methoxyindan-1-one oxime

HRID 1612240Notes

Reaction equation

HRID 1612240 reaction equation
O1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)/[C:4](=[N:11]/[OH:12])/[CH2:3][CH2:2]1.[CH3:13][O:14]C1C=C2C(=CC=1)C(=O)CC2>>[CH3:13][O:14][C:8]1[CH:7]=[C:6]2[C:5](=[CH:10][CH:9]=1)[C:4](=[N:11][OH:12])[CH2:3][CH2:2]2

Participants

3

Reactant 2

HCID 787875-Methoxyindan-1-oneHCID 9673039Chroman-4-one oxime

Product 1

HCID 2881895-Methoxyindan-1-one oxime

Procedure

Following the procedure for the preparation of (4E)-2,3-dihydro-4H-chromen-4-one oxime but substituting 5-methoxyindan-1-one and making non-critical variations provided the title compound as a oil: HRMS (EI) calcd for C10H11O2 177.0790, found 177.0783. Anal. Calcd for C10H11NO2: C, 67.78; H, 6.26; N, 7.90. Found: C, 67.73; H, 6.34; N, 7.77.

Sources & evidence

ORD record
ord-d5d81237e7e54138ada24baa14b96412
Source dataset
uspto-grants-2006_01
Patent number
US06992087B2

Reaction notes

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