Ethyl-1-indanone → 2-ethyl-2,3-dihydro-1H-inden-1-one oxime

HRID 1612261Notes

Reaction equation

HRID 1612261 reaction equation
O1C2C(=CC=CC=2)/C(=[N:11]/[OH:12])/CC1.[CH2:13]([CH:15]1[CH2:23][C:22]2[C:17](=[CH:18][CH:19]=[CH:20][CH:21]=2)[C:16]1=O)[CH3:14]>>[CH2:13]([CH:15]1[CH2:23][C:22]2[C:17](=[CH:18][CH:19]=[CH:20][CH:21]=2)[C:16]1=[N:11][OH:12])[CH3:14]

Participants

3

Reactant 2

HCID 5070076Ethyl-1-indanoneHCID 9673039Chroman-4-one oxime

Product 1

HCID 738670832-ethyl-2,3-dihydro-1H-inden-1-one oxime

Procedure

Following the procedure for the preparation of (4E)-2,3-dihydro-4H-chromen-4-one oxime but substituting (+/−)-2-ethyl-2,3-dihydro-1H-inden-1-one and making non-critical variations provided the title compound as a colorless syrup. MS (ESI+) for m/z 176.1 (M+H)+.

Sources & evidence

ORD record
ord-9400e1f8a5b540689adde0d6b5141f6d
Source dataset
uspto-grants-2006_01
Patent number
US06992087B2

Reaction notes

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