huagongshe.com
HRID1612527

反应详情

EQUATION

反应方程式

HRID 1612527 的结构方程式

REACTANTS

反应物

1
结构：CC(=O)OC(CO)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(=O)COCCOCCN=[N+]=[N-]
HCID86585969

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)OC(CO)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(=O)COCCOCCN
HCID23593511

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Ni]
催化剂HCID935

Nickel

Ni

结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

In a hydrogenation apparatus, a suspension of 1.12 g of 2,3,4-triacetoxy-1-{2-[2-(2-azido-ethoxy)ethoxy]acetyl}-5-hydroxypentyl acetate and 1.0 g of Raney-Nickel in 100 ml of ethanol is shaken under an atmosphere of hydrogen for 4 h. The reaction solution is filtered and concentrated. The residue contains 23:

WORKUP

后处理

  1. filtrationThe reaction solution is filtered
  2. concentrationconcentrated