HuagongsheHuagongshe Chemistry Print Report · For research reference only
Quinoline → (Z)-dodec-2-en-1-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Quinoline | HCID 7047 | — |
| Reactant | Dodec-2-yn-1-ol | HCID 1712322 | — |
| Reactant | 2-Decen-1-ol, (Z)- | HCID 5364953 | — |
| Product | (Z)-dodec-2-en-1-ol | HCID 5364955 | — |
Reaction Steps
cis-2-Dodecen-1-ol was prepared as described above for cis-2-decen-1-ol except that 35 g of 2-dodecyn-1-ol, 1.0 g of catalyst, and 3.0 ml of quinoline was used. A clear oil, 33.86 g, was obtained after kugelrohr distillation. 1H NMR δ5.57 (m, 2), 4.19 (d, 2, J=5 Hz), 2.07 (dd, 2, J=6, 12 Hz), 1.5-1.2 (m, 14), 0.88 (t, 3, J=7 HZ).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05190969 |
| Source dataset | uspto-grants-1993_03 |
| ORD ID | ord-29c445e10cd84eda8e1d41d37cdfb73e |
| Source note | uspto-grants-1993_03 |