1,1'-(Chloromethylene)bis(4-fluorobenzene) → HCID 19776768, compound

HRID 1612839Notes

Reaction equation

[F:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8](Cl)[C:9]2[CH:14]=[CH:13][C:12]([F:15])=[CH:11][CH:10]=2)=[CH:4][CH:3]=1.[OH:17][CH:18]1[CH2:23][CH2:22][N:21]([CH2:24][CH2:25][CH2:26][O:27][C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][C:29]=2[N+:34]([O-:36])=[O:35])[CH2:20][CH2:19]1>>[F:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]([C:9]2[CH:14]=[CH:13][C:12]([F:15])=[CH:11][CH:10]=2)[O:17][CH:18]2[CH2:19][CH2:20][N:21]([CH2:24][CH2:25][CH2:26][O:27][C:28]3[CH:33]=[CH:32][CH:31]=[CH:30][C:29]=3[N+:34]([O-:36])=[O:35])[CH2:22][CH2:23]2)=[CH:4][CH:3]=1

Participants

Reactant 2

HCID 27237731,1'-(Chloromethylene)bis(4-fluorobenzene)

HCID 197767934-Hydroxy-1-[3-(2-nitrophenoxy)propyl]piperidine2×

Product 1

HCID 19776768HCID 19776768, compound

Procedure

The procedure of Example 1 (a) was repeated except for using di(4-fluorophenyl)methyl chloride and 4-hydroxy-1-[3-(2-nitrophenoxy)propyl]piperidine instead of diphenylmethyl bromide and 4-hydroxy-1-[3-(2-nitrophenoxy)propyl]piperidine to give oily 4-di(4-fluorophenyl)methoxy-1-[3-(2-nitrophenoxy)propyl]piperidine.

Sources & evidence

ORD record: ord-896e72bc013d49cd8ccb81236f62e1a8
Source dataset: uspto-grants-1993_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05190959

Reaction notes

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