Phenol → Trihexyl borate

HRID 1613121Notes

Reaction equation

HRID 1613121 reaction equation
[C:1]1(OB(O)O)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:11][O:12][B:13]([OH:15])[OH:14].[C:16]1(O)[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1>>[B:13]([O:15][CH2:1][CH2:6][CH2:5][CH2:4][CH2:3][CH3:2])([O:14][CH2:16][CH2:21][CH2:20][CH2:19][CH2:18][CH3:17])[O:12][CH2:11][CH2:3][CH2:2][CH2:1][CH2:6][CH3:5]

Participants

4

Reactant 3

HCID 996PhenolHCID 78412Phenyl dihydrogen orthoborateHCID 14178740Methylborat

Product 1

HCID 21423Trihexyl borate

Procedure

Reaction is conducted in the same manner as described above except that phenylboric acid or methylboric acid is used instead of boric acid in the above example and a corresponding alcohol or phenol is used instead of hexyl alcohol, and then, the solvent is concentrated under reduced pressure, followed by distillation or crystallization and recrystallization with an appropriate solvent, whereby a corresponding boron compound can be obtained.

Workup

  1. customReaction
  2. concentrationthe solvent is concentrated under reduced pressure
  3. distillationfollowed by distillation or crystallization and recrystallization with an appropriate solvent, whereby a corresponding boron compound
  4. customcan be obtained

Sources & evidence

ORD record
ord-e7e8e5e7ab61454aa33954f41c1a59fd
Source dataset
uspto-grants-1993_03
Patent number
US05192650

Reaction notes

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