Ethyl (1,2,3,4-tetrahydronaphthalen-1-yl)acetate → 1-Naphthaleneacetic acid, 3,4-dihydro-, ethyl ester

HRID 1613574Notes

Reaction equation

HRID 1613574 reaction equation
C1(CC(O)=O)C2C(=CC=CC=2)CCC1.[CH2:15]([O:17][C:18]([CH2:20][CH:21]1[C:30]2[C:25](=[CH:26][CH:27]=[CH:28][CH:29]=2)[CH2:24][CH2:23][CH2:22]1)=[O:19])[CH3:16]>>[CH2:15]([O:17][C:18]([CH2:20][C:21]1[C:30]2[C:25](=[CH:26][CH:27]=[CH:28][CH:29]=2)[CH2:24][CH2:23][CH:22]=1)=[O:19])[CH3:16]

Participants

3

Reactant 2

HCID 12322859Ethyl (1,2,3,4-tetrahydronaphthalen-1-yl)acetateHCID 128585751,2,3,4-Tetrahydro-1-naphthaleneacetic acid

Product 1

HCID 109109471-Naphthaleneacetic acid, 3,4-dihydro-, ethyl ester

Procedure

(1,2,3,4-tetrahydronaphthalen-1-yl)-acetic acid was itself prepared from 1-ethoxycarbonylmethyl-1,2,3,4-tetrahydronaphthalene, which was obtained from 1-ethoxycarbonylmethyl-3,4-dihydronaphthalene [cf. J. Chem. Soc. (1960), 4115-4120], which was itself prepared from 1,2,3,4-tetrahydronaphthalen-1-one.

Sources & evidence

ORD record
ord-30f2f00103244743b4763e9ad5d86b80
Source dataset
uspto-grants-1993_03
Patent number
US05194437

Reaction notes

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