2-(2,4-Dichlorophenoxy)ethanol → 2-(2,4-Dichlorophenoxy)ethanol sulfamate

HRID 1613760Notes

Reaction equation

HRID 1613760 reaction equation
[S:1](Cl)(=[O:4])(=[O:3])[NH2:2].[Cl:6][C:7]1[CH:16]=[C:15]([Cl:17])[CH:14]=[CH:13][C:8]=1[O:9][CH2:10][CH2:11][OH:12]>>[S:1]([O:12][CH2:11][CH2:10][O:9][C:8]1[CH:13]=[CH:14][C:15]([Cl:17])=[CH:16][C:7]=1[Cl:6])(=[O:4])(=[O:3])[NH2:2]

Participants

3

Reactant 2

HCID 84442-(2,4-Dichlorophenoxy)ethanolHCID 24499Chlorosulfamic acid

Product 1

HCID 191086892-(2,4-Dichlorophenoxy)ethanol sulfamate

Procedure

The title compound was prepared by the procedures of Example 33 from sulfamoyl chloride and 2-(2,4-dichlorophenoxy)ethanol. The viscous oil obtained solidified and was recrystallized from isopropyl ether to give the solid title compound, mp 75°-77° C., in 35% yield.

Workup

  1. customThe viscous oil obtained solidified
  2. customwas recrystallized from isopropyl ether

Sources & evidence

ORD record
ord-a30a380b49f140ffa744e3b9359ef58f
Source dataset
uspto-grants-1993_03
Patent number
US05194446

Reaction notes

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